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Changing Your Working Directory
When you start a dialog to open or save a document, LibreOffice initially displays your work directory. To change this directory:
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Choose LibreOffice - PreferencesTools - Options - LibreOffice - Paths.
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Click \My Documents \and click the\ Edit button, or \double-click on \My Documents\.
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In the \Select Path\ dialog, choose the work directory you want and click \OK\.
You also use this procedure to change the directory displayed by LibreOffice when you want to insert a graphic. Choose LibreOffice - PreferencesTools - Options - LibreOffice - Paths - Images, then follow step 3.
Paths